沼氣濕式法脫硫技術(shù)包括堿性溶液吸收法、萘醌氧化法、HAPS氧化法、PDS法等。堿性溶液法吸收H2S[30]，采用逆流接觸，反應(yīng)如下：

The wet desulfurization technology of biogas includes alkaline solution absorption method, naphthoquinone oxidation method, HAPS oxidation method, PDS method, etc. The alkaline solution method absorbs H2S [30], using countercurrent contact, and the reaction is as follows:

吸收受到流速、流量、溫度、氣量、停留時(shí)間等因素的影響，溶解度很難保證100％，易形成NaHS，而非Na2S。NaHS再生時(shí)與氧氣反應(yīng)生成硫酸鹽和硫代硫酸鹽，降低吸收液的吸收能力，從而堿液需要定期更換，也可能帶來(lái)二次污染。

The absorption is affected by factors such as flow rate, flow rate, temperature, gas volume, and residence time, making it difficult to ensure 100% solubility and easy to form NaHS instead of Na2S. During NaHS regeneration, it reacts with oxygen to generate sulfates and thiosulfates, reducing the absorption capacity of the absorption solution. As a result, the alkaline solution needs to be replaced regularly and may also cause secondary pollution.

萘醌氧化法是氧化H2S成為S單質(zhì)，從而脫除H2S，回收硫，此法具有合適的氧化還原電位，易操作等優(yōu)點(diǎn)。HAPS氧化法是以Na3PMo12O40、NaCl、Na2CO3和NaVO3的混合液作吸收液，常溫下將H2S轉(zhuǎn)化為S單質(zhì)，使用后的HAPS經(jīng)氧氣氧化再生后可循環(huán)使用，S單質(zhì)分離回收。PDS法為鈦箐鈷磺酸鹽系化合物的混合物，脫除H2S具有工藝簡(jiǎn)單、成本低、效果好等優(yōu)點(diǎn)。

The naphthoquinone oxidation method oxidizes H2S into elemental S, thereby removing H2S and recovering sulfur. This method has the advantages of suitable redox potential and easy operation. The HAPS oxidation method uses a mixture of Na3PMo12O40, NaCl, Na2CO3, and NaVO3 as the absorption solution to convert H2S into elemental S at room temperature. The used HAPS can be recycled after oxygen oxidation regeneration, and elemental S can be separated and recovered. The PDS method is a mixture of titanium cobalt sulfonate compounds, which has the advantages of simple process, low cost, and good effect in removing H2S.

在能源越來(lái)越緊張，環(huán)保要求越來(lái)越高的形勢(shì)下，沼氣利用對(duì)豐富和完善能源結(jié)構(gòu)，緩解能源供需不平衡，提高可再生資源利用率，減少不可再生能源消耗，避免廢棄物造成環(huán)境污染，降低工業(yè)、農(nóng)牧業(yè)、養(yǎng)殖業(yè)生成成本，提升副產(chǎn)品利用價(jià)值有切實(shí)的意義。因此，沼氣技術(shù)發(fā)展需要注意以下幾點(diǎn)：

In the context of increasingly scarce energy and higher environmental requirements, the utilization of biogas has practical significance in enriching and improving the energy structure, alleviating the imbalance between energy supply and demand, improving the utilization rate of renewable resources, reducing non renewable energy consumption, avoiding environmental pollution caused by waste, reducing the production costs of industry, agriculture, animal husbandry, and animal husbandry, and enhancing the value of by-product utilization. Therefore, the development of biogas technology needs to pay attention to the following points:

完善可再生能源激勵(lì)政策，針對(duì)沼氣工程的能量多層次利用和物質(zhì)循環(huán)利用，既產(chǎn)生節(jié)能減排的公益性又帶來(lái)環(huán)境效益，政府應(yīng)加大財(cái)政補(bǔ)貼和扶持力度，給予一些優(yōu)惠政策，鼓勵(lì)發(fā)展；

Improve incentive policies for renewable energy, targeting the multi-level utilization of energy and material recycling in biogas projects, which not only generates public benefits such as energy conservation and emission reduction, but also brings environmental benefits. The government should increase financial subsidies and support, provide some preferential policies, and encourage development;

加強(qiáng)沼氣工程新技術(shù)和新設(shè)備研發(fā)，提高效率，降低工程成本。尤其是適合偏遠(yuǎn)地區(qū)和孤島等地綜合利用的小型沼氣利用技術(shù)開(kāi)發(fā)；

Strengthen the research and development of new technologies and equipment for biogas engineering, improve efficiency, and reduce project costs. Especially for the development of small-scale biogas utilization technologies suitable for comprehensive utilization in remote areas and isolated islands;

對(duì)多原料高濃度聯(lián)合發(fā)酵技術(shù)研究，保證產(chǎn)氣原料充足，提高裝置產(chǎn)氣率。沼氣工程向集中化、大型化的方向發(fā)展，提高工程經(jīng)濟(jì)性和能源效率；

Research on high concentration co fermentation technology with multiple raw materials to ensure sufficient gas production raw materials and improve the gas production rate of the equipment. The biogas engineering is developing towards centralization and large-scale, improving the economic efficiency and energy efficiency of the project;

沼氣發(fā)電和用于燃料電池，是有效利用沼氣資源的新途徑，具有很大的發(fā)展?jié)摿Γ?/p>

Biogas power generation and its use in fuel cells are new ways to effectively utilize biogas resources and have great development potential;

沼氣綜合利用技術(shù)開(kāi)發(fā)，開(kāi)展沼氣提純技術(shù)，可使沼氣注入天然氣網(wǎng)用做燃料，或代替汽油、柴油用于車輛，實(shí)現(xiàn)沼氣利用高端化，提高能源效益。

The development of biogas comprehensive utilization technology and the implementation of biogas purification technology can inject biogas into the natural gas network for fuel, or replace gasoline and diesel for vehicles, achieving high-end utilization of biogas and improving energy efficiency.

完善和合理規(guī)劃養(yǎng)殖與種植產(chǎn)業(yè)布局，實(shí)現(xiàn)資源綜合平衡利用，減少輸送成本，提高效益。

Improve and reasonably plan the layout of aquaculture and planting industries, achieve comprehensive and balanced utilization of resources, reduce transportation costs, and improve efficiency.

推廣沼氣農(nóng)村發(fā)展，前景十分廣闊；

The promotion of biogas for rural development has a very broad prospect;

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